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recyclability 3

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preparation of Ag@AgCl/Bio-veins composites and their photocatalytic activity and recyclability

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 7, Pages 906-917 doi: 10.1007/s11705-022-2273-9

Abstract: Furthermore, the composites also exhibited excellent recyclability and stability under both visible and

Keywords： Ag@AgCl biological veins photocatalytic activity recyclability

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Hyperbranched magnetic polymer: highly efficient removal of Cr(VI) and application in electroplating wastewater

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10, Pages 1568-1580 doi: 10.1007/s11705-023-2303-2

Abstract: By using a two-step hydrothermal method and trithiocyanuric acid (TTCA), 2,4,6-trihydrazino-1,3,5-triazine (THT), and Fe₃O₄ as raw materials, a spherical magnetic adsorbent polymer (TTCA/THT@Fe₃O₄) was synthesized to achieve the efficient removal of Cr(VI) from wastewater. Under optimal adsorption conditions, the maximum adsorption capacity of TTCA/THT@Fe₃O₄ for Cr(VI) can reach 1340 mg∙g^‒1. Notably, the removal efficiency can approach 98.9%, even at the lower concentration of 20 mg∙L^‒1 Cr(VI). For actual wastewater containing Cr(VI), the Cr(VI) concentration was reduced from 25.8 to 0.4 mg∙L^‒1, a remarkable 20% lower than the current industry discharge standard value. A mechanism for the high adsorption performance of Cr(VI) on TTCA/THT@Fe₃O₄ was investigated using Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and density functional theory. It can be plausibly attributed to the formation of Cr/N and Cr/S coordination bonds. Additionally, surface electrostatic adsorption, reduction effects, and the spherical polymer structure increase the contact area with Cr(VI), maximizing adsorption. The synergistic effect of adsorption and reduction enhances the adsorption performance of TTCA/THT@Fe₃O₄ for Cr(VI) and total chromium in water. The resultant polymer has a simple preparation process, excellent adsorption performance, easy magnetic separation, and promising application for actual wastewater.

Keywords： magnetic polymer chromium removal hydrogen bonding recyclability actual wastewater

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Pd/Fe3O4 supported on bio-waste derived cellulosic-carbon as a nanocatalyst for C–C coupling and electrocatalytic application

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 10, Pages 1514-1525 doi: 10.1007/s11705-022-2158-y

Abstract: The current work describes the synthesis of a new bio-waste derived cellulosic-carbon supported-palladium nanoparticles enriched magnetic nanocatalyst (Pd/Fe₃O₄@C) using a simple multi-step process under aerobic conditions. Under mild reaction conditions, the Pd/Fe₃O₄@C magnetic nanocatalyst demonstrated excellent catalytic activity in the Hiyama cross-coupling reaction for a variety of substrates. Also, the Pd/Fe₃O₄@C magnetic nanocatalyst exhibited excellent catalytic activity up to five recycles without significant catalytic activity loss in the Hiyama cross-coupling reaction. Also, we explored the use of Pd/Fe₃O₄@C magnetic nanocatalyst as an electrocatalyst for hydrogen evolution reaction. Interestingly, the Pd/Fe₃O₄@C magnetic nanocatalyst exhibited better electrochemical activity compared to bare carbon and magnetite (Fe₃O₄ nanoparticles) with an overpotential of 293 mV at a current density of 10 mA·cm^–2.

Keywords： cellulosic-carbon Pd/Fe₃O₄ Hiyama cross-coupling hydrogen evolution reaction recyclability